I gig with it regularly, always moved with a cover on it, stored in a nice dry clean room. Those are backplate 6v6s. Should i try to clean it off? It's only on that one tube.
I would try a paper towel or napkin dampened with a bit of water to scrub that off. Try not to get the damp paper on the "6V6" stamp or any logo printing on the glass; it's very easy to wash off the labeling on old tubes.
If water doesn't get it clean, alcohol or naphtha definitely will (or use Goo Gone or similar if that's what you have on hand).